A novel synthetic approach to the bicyclo[5.3.1]undecan-11-one framework of vinigrol.
نویسندگان
چکیده
The first synthetic attempt commencing from an eight-membered ring to approach the [5.3.1] bicyclic core of vinigrol has demonstrated the feasibility of using the conformational bias of the cyclooctane-ring system to realize highly diastereoselective reactions. The synthetic potential of the newly disclosed access to in/out isomerism may stimulate broader interests.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 12 22 شماره
صفحات -
تاریخ انتشار 2014